环境因素对BT80S-5Cr抗CO2/H2S腐蚀套管均匀腐蚀速率的影响

    Effect of Environmental Factors on Uniform Corrosion Rate of BT80S-5Cr Anti-CO2/H2S Corrosion Casing

    • 摘要: 通过模拟国内某油田腐蚀工况,采用高温高压釜模拟腐蚀试验,利用失重法研究试验周期、温度、CO2及H2S分压环境因素对BT80S-5Cr油套管均匀腐蚀速率的影响。研究表明,随着试验周期的延长,试验钢均匀腐蚀速率逐渐降低,且降幅趋于平缓,试验周期360 h是BT80S-5Cr在该油气田模拟工况下衡量耐蚀性能的最佳试验周期;随着试验温度的提高,试验钢均匀腐蚀速率逐渐增加,试验温度100℃的试验钢的均匀腐蚀速率是试验温度40℃时的均匀腐蚀速率的1.67倍;随着CO2分压的提高,试验钢均匀腐蚀速率逐渐增加,CO2分压1.0 MPa的试验钢均匀腐蚀速率是不含CO2时的均匀腐蚀速率的10倍;随着H2S分压的提高,试验钢均匀腐蚀速率逐渐降低,微量H2S气体的引入对试验钢电化学腐蚀行为有一定的抑制作用。

       

      Abstract: For simulation the corrosive working conditions of a certain domestic oil field,the corrosion test is conducted with the high temperature/high pressure caldron and the weight loss method to investigate the effects of relevant environmental factors on the uniform corrosion rate of the BT80S-5Cr oil casing,including the test cycle,the temperature and the CO2 and H2S partial pressures. The results show that along with the extension of the test period,the uniform corrosion rate of the test steel gradually decreases,and the decrease tends to be steady and slow;and the test period of 360 h is the best test period for the BT80S-5Cr steel to measure the corrosion resistance under the simulated working conditions of the said oil/gas field;with the increase of test temperature,the uniform corrosion rate of the test steel gradually increases;the uniform corrosion rate of the test steel as tested at 100 ℃ is 1.67 times that of the test steel as tested at 40 ℃;With the increase of the CO2 partial pressure,the uniform corrosion rate of the test steel gradually increases,and the uniform corrosion rate of the test steel with a partial pressure of CO2 of 1.0 MPa is 10 times that of the test steel free of CO2;along with the increase of the H2S partial pressure,the uniform corrosion rate of the test steel gradually decreases,and the introduction of trace H2S gas has a certain inhibitory effect on the electrochemical corrosion behavior of the test steel.

       

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