高铬奥氏体耐热钢管内壁喷丸处理对抗蒸汽氧化性能的影响

    Influence by Inner Wall Shot Blast Process on Steam Oxidation Resistance of High-Cr Austenitic Heat-resistant Steel Tube

    • 摘要: 为评估内壁喷丸处理对高铬奥氏体耐热钢抗蒸汽氧化性能的影响,选取S31035、SP2215、TP310HCbN三种钢管在未喷丸与喷丸两种状态下进行665℃、3 000 h高温水蒸气氧化试验。通过氧化膜厚度测量、XRD物相分析、SEM/EDS显微表征,系统研究了氧化层结构演变规律,并基于氧化动力学曲线外推10万h腐蚀数据。结果表明:喷丸处理未显著提升抗蒸汽氧化性能,两种状态下氧化膜生长速率与物相组成相近;从工程应用角度看,3种钢管的喷丸与未喷丸试样均满足腐蚀裕量标准要求;建议取消喷丸工艺,以降低生产成本。

       

      Abstract: In order to investigate the influence by the inner surface shot blasting process on steam oxidation resistance of the hi-chromium austenitic heat-resistant steel tube,three types of the high chromium austenitic heat-resistant steel tube,i.e.,S31035,SP2215 and TP310HCbN are subjected to high-temperature steam oxidation experiments at 665 ℃for a maximum of 3 000 h in both non-shot blasted and shot blasted states. The evolution law of the oxide layer structure is systematically studied by means of oxidation film thickness measurement,the X-ray diffraction,scanning electron microscopy and energy dispersive spectroscopy,and based on the oxidation kinetics curve,the 100 000 h corrosion data are extrapolated.As a result,the facts as follows are revealed. The shot blasting treatment can not obviously increase the steam oxidation resistance of the pipe,and in the above mentioned two states,the oxide film growth rate is close to the object composition;and from an engineering perspective,both the shot-blasted and the non-shot blasted specimens of the said three tubes are in compliance with the corrosion allowance as required under applicable specification. Accordingly it is recommended to cancel the shot blasting treatment for the said three types of tubes so as to reduce the production cost.

       

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