加工工艺对304不锈钢管材晶间腐蚀行为的影响

    Influences of Different Process Technologies on Intergranular Corrosion Behavior of 304 Stainless Steel Tubular Product

    • 摘要: 系统考察了304不锈钢管材在不同加工工艺下的晶间腐蚀行为。通过对比分析切管、弯管、水胀、热处理及抛光等关键工序对材料微观组织及耐蚀性的影响,发现宏观尺度(10~200倍)下所有工艺试样均未出现明显晶间腐蚀,满足标准要求;微观尺度(500倍)下:弯管后热处理试样出现轻微晶间腐蚀,水胀工艺使腐蚀加剧,水胀+热处理后腐蚀仍显著存在,抛光工序导致最严重的晶间腐蚀。变形组织分析表明:弯管外层形成的变形组织在压扁时易开裂,但热处理可消除该组织并改善开裂倾向。建议改进抛光工艺参数并引入钝化处理,可显著提升管材耐蚀性能。

       

      Abstract: Systematically investigated here in the article are the intergranular corrosion behaviors of the 304 stainless steel tubular product as going through different processing technologies. Also comparatively analyzed are the influences on the microstructure and corrosion resistance of the material by such process steps as tube cutting and bending,water expanding,heat treatment and polishing,etc.,and then it is revealed that in case of the macro size,i.e.,10~200 magnification,none of the process specimen presents any intergranular corrosion,being up to the requirement of applicable specification;while in case of the micro size,i. e.,500 magnification,the post-bending heat treatment specimen presents slight intergranular corrosion;the corrosion is getting more and more serious with the water-expanding process,and even after the water-expanding plus the heat treatment,the corrosion still remains obviously;the polishing process leads to the most serious intergranular corrosion;the analysis of the deformation structure shows that the deformation structure in the external layer of the elbow as being flattened is easy to crack;however heat treatment can eliminate such structure,and get the cracking trend improved. It is finally recommended to improve the polishing process parameters,and add the passivation treatment so as to remarkably enhance the corrosion resistance of the tubular product.

       

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