管道环氧涂层固化度与玻璃化转变温度关系的研究

    Study on Relation between Curing Degree of Epoxy Coating and Glass-transition Temperature of Pipeline

    • 摘要: 针对国内油气输送用热煨弯管双层熔结环氧粉末外防腐标准中取消环氧粉末固化度,改用两次试验条件下加热测得的涂层玻璃化转变温差值ΔTg来评价涂层的固化情况,指出ΔTg不能直观地计算得出,有必要研究固化百分率与玻璃化转变温度的关系。利用DSC扫描仪测定环氧粉末的玻璃化转变温度Tg3Tg4及其差值ΔTg,用涂层固化后剩余焓变计算固化百分率C,然后拟合固化百分率与ΔTg的对应关系。分析结果可直观反映出玻璃化转变温度ΔTg与固化度的关系,对产品制造过程中的质量把控具有指导和推动作用。

       

      Abstract: In the updated applicable national specifications in association with using dual-layer fusion epoxy powder method for outer surface corrosion-prevention of the hot-bend pipe for oil/gas transmission, the concept of epoxy powder curing degree has been removed, instead, the glass-transition temperature ΔTg as measured twice from the heated coating under two testing conditions is used to evaluate the curing condition of the coating.It is pointed out that the ΔTg value can not be directly calculated, and thus it is necessary to study the relation between the cure percentage and the glasstransition temperature is studied.And the glass-transition temperatures of the epoxy powder Tg3 and Tg4 and their difference ΔTg are measured by the DSCscanner.And then thecurepercentage C iscalculated with the enthalpy changeremained after thecoatingiscured, and thecorrespondence between the cure percentage C and ΔTg is fit.And this relation can be directly reflected via the analysis, which can play a quality guiding and promoting role in the manufacturing process of the product.

       

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